WINDOW FACTOR ANALYSIS:THEORETICAL DERIVATION AND APPLICATION TO FLOW INJECTION ANALYSIS DATA   总被引：1，自引：0，他引：1  

EDMUND R.MALINOWSKI 《地理学报(英文版)》1992,(1)

Window factor analysis(WFA)is a self-modeling method for extracting the concentration profiles ofindividual components from evolutionary processes such as flow injection,chromatography,titrationsand reaction kinetics.The method takes advantage of the fact that each component lies in a specificregion along the evolutionary axis,called the‘window’.Theoretical equations are derived.The methodis used to extract the concentration profiles and spectra of seven bismuth species from data obtained byGemperline and Hamilton,who injected bismuth perchlorate into a flowing stream of hydrochloric acid.  相似文献   

Biological and physical events involved in the origin,effects, and control of organic matter in solar saltworks     

Joseph S. Davis  Mario Giordano 《International Journal of Salt Lake Research》1995,4(4):335-347

Aspects of communities and events in the concentrating ponds (S.G. 1.130 to 1.214) and salt crystallizing ponds (S.G. 1.215 to 1.264) of solar saltworks pertinent to salt manufacture are described. Communities that aid salt manufacture enable continuous and efficient production of high quality salt at a saltworks' design capacity, and they provide important controls on levels of organic matter in the brine. Fluctuating salinities, high concentrations of nutrients, and petroleum products are disturbances that causeAphanothece halophytica andDunaliella salina to release excessive quantities of organic matter, and that suppress or cause death to nutrient stripping organisms. Disturbances result in decreased quality and quantity of salt and increased costs for salt harvest, washing, and pond upkeep. Organic matter can be controlled by management techniques that keep nutrient stripping communities at proper levels and maintain a narrow and unchanging range of salinities in each pond, by constructing pond dikes able to withstand wind and water erosion, and by preventing spills of petroleum products in the ponds.  相似文献   

FTIR studies of reactions between the nitrate radical and haloethenes     

I. M. W. Noremsaune  J. Hjorth  C. J. Nielsen 《Journal of Atmospheric Chemistry》1995,21(3):223-250

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.  相似文献   

H~+,Li~+,Mg~(2+)∥Cl~-—H_2O四元水盐体系在-10℃时的平衡溶解度相图     

王继顺  高世扬  刘铸唐  王波 《盐湖研究》1993,(2)

本文利用等温溶解度法测定了H~+,Li~+,Mg~(2+)//Cl~-—H_2O四元水盐体系在—10℃±0.1℃时的溶解度并绘制了等温相图。相图由HCl·MgCl_2·7H_2O、MgCl_2·8H_2O、HCl·6H_2O和LiCl·2H_2O四个相区构成,只有一个零变量点I:LiCl·2H_2O+MgCl_2·6H_2O+HCl·MgCl_2·7H_2O+L_(?)利用坐标变换和直线外推法,对溶解度数据进行处理后,用湿渣结线法解决了低温平衡固相较难确定的问题。  相似文献   

高温铀物种形成(Speciation)的热力学数据     

黄克玲  周鲁民  张景廉 《铀矿地质》1993,(6)

本文依据C.M.Criss和J.W.Cobble的“离子熵对应原理”,对1978年D.Langmuir给出的铀物种形成常温热力学数据进行了高温值的处理,得出了一套较全面而系统的高温热力学参数,以供参考使用。  相似文献   

钨、锡流-熔分配实验结果及其矿床成因意义   总被引：4，自引：1，他引：4  

陈子龙  彭省临 《地质论评》1994,40(3):274-282

本文用实验确定了钨、锡在成分不同的花岗质熔体相与共存水热流体相的流-熔分配系数(D_(Me)~(V/L))及其与介质溶液(NaF,KF,HF,NaCl等水溶液)摩尔浓度间的函数关系。实验结果表明,钨、锡的分配行为明显不同。在相同条件下,随体系的不同,D_W~(V/L)比D_(Sn)~(V/L)大几倍至二十倍。钠和钾对钨、锡的流-熔分配行为的影响基本相同,而氟和氯对钨、锡的分配行为的影响相差甚远,花岗质熔体的主成分对D_W~(V/L)和D_(Sn)~(V/L)有复杂的影响。利用这些结果探讨与花岗岩有关的钨、锡矿床的成矿机理,得出了一些与前人不同的新认识。  相似文献   

无水氯化镍及芳烃基二膦酸四乙酯的制备          下载免费PDF全文

董亚萍 《盐湖研究》1997,5(2):57-63

1，4—二溴苯，4，4’—二溴联苯、4，4’—二溴三联和亚磷酸三乙酯在催化剂无氯化镍催化下，干燥氮气保护．反应得到相应的有机二磷酸四乙酯。  相似文献   

唐古拉山冬克玛底冰川雪层中淋溶作用的初步研究   总被引：7，自引：7，他引：7  

侯书贵  秦大河 《冰川冻土》1996,18(3):227-234

利用唐古拉山冬克玛底冰川雪坑和表层积雪样品的实测资料，初步探讨本区雪层中离子淋溶作用的特征，影响因素及其对冰芯记录的干扰。研究发现淋溶作用能够对数周至数月时间尺度的雪层记录产生“平滑”作用，但不会影响冰芯记录的长期变化趋势。  相似文献   

确定干旱—半干旱地区降水入渗补给量的新方法——氯离子示踪法   总被引：7，自引：0，他引：7  

陈植华  徐恒力 《地质科技情报》1996,15(3):87-92

在干旱－半干旱地区由于入渗水分大部分滞留在包气带中，强烈地蒸发、蒸作用导致包气带中土壤水的氯离子浓度改变。氯离子示踪方法从质量守恒角度，通过比较土壤水分的氯离子浓度和降水输入的氯离子浓度大小，可以定量确定降水入渗量和降水入渗补给的历史变化过程。本文介绍了目前国外应用较普遍的氯离子均衡法和氯离子累积法，并讨论了方法应用时存在的一些问题。  相似文献   

湘南稀土矿床的放射性特征及其对开采的影响     

谭光贵 《湖南地质》1996,15(4):229-233

湘南主要稀土矿区的岩、矿石和稀土矿物的放射性特征表明，矿区放射性强度的高低与稀土总量无关，而与矿石的铀、钍含量密切相关；主要矿区的放射性对其开发与产品都没有影响，但长期接触对人体有一定危害。因此，开采时必须加强防护，防止放射性的长期照射，并选用无放射性的清洁饮用水，以保护人体健康。  相似文献